| 1. | Flushed Into an Alternate World |
| 2. | Duel! Hot Boy vs. Baseball Boy |
| 3. | Yuri Shibuya! I AM the Demon King! |
| 4. | What`s Next? The Ultimate Weapon? |
| 5. | Sailors AND a Spoiled Brat |
| 6. | The Terror Of Morgif, A Man-Eating Demon Sword? |
| 7. | Runaway? Stray? Demon Sword in Motion! |
| 8. | Moonlit Plot |
| 9. | Stolen Treasure |
| 10. | The Hand of Evil Looms Closer! |
| 11. | The War Begins in the Alternate |
| 14. | Yuri Does Heavy Labor |
| 15. | Rainfall in the Desert |
| 16. | The Demon King Case File! |
| 17. | I`m Remarrying |
| 18. | In the Name of Love |
| 19. | Hero vs. Demon King - Part 1 |
| 20. | Hero vs. Demon King - Part 2 |
| 21. | The Dangerous Visitor |
| 22. | Man of Destiny |
| 23. | Race of Flame |
| 24. | Unforgiven |
| 25. | The Past and Future |
| 26. | The Full Circle of Life |
| 27. | Conrad`s Arm |
| 28. | Atrocious Reunion |
| 29. | Chilling Overture |
| 30. | A Forbidden Box |
| 31. | The Ends of the Earth |
| 32. | The Locked Memory |
| 33. | Run For It! The Snow Sled Race |
| 34. | Hot Battle Coliseum?! |
| 35. | Snow-Covered Earth |
| 36. | Farewell Conrad |
| 37. | Whereabouts of the Boxes |
| 38. | Gunter vs. Conrad |
| 39. | Your Name Is Demon King |
| 40. | For Our Bonds |
| 41. | Conrad`s Return |
| 42. | A Distant Promise |
| 43. | Baby Panic at Covenant Castle! |
| 44. | The Phantom Girl |
| 45. | The Betrothed vs. the Fiance |
| 46. | The Priestess in the Forest |
| 47. | Proof of Life |
| 48. | Big Cimaron Strikes Back! |
| 49. | The Lion and the Wolf |
| 50. | My Beloved Julia |
| 51. | Revenge Fiend? Maxine |
| 52. | Conrad Standing Tall |
| 53. | Dear King Yuri |
| 54. | The Holy Sword and the Demon Sword (Part 1) |
| 55. | The Holy Sword and the Demon Sword (Part 2) |
| 56. | The Shadow Begins to Move |
| 57. | The Creature from the Darkness |
| 58. | The King of Chaos |
| 59. | Demons, To Earth |
| 60. | Big Brother`s Anguish |
| 61. | Another Demon King |
| 62. | Entrusted Hope |
| 63. | Showdown! Demon King vs. Koch Army |
| 64. | Snow Gunter Again |
| 65. | One Who Braves the Snow |
| 66. | Feeling of Power |
| 67. | The Bridge We Hang Upon Tomorrow |
| 68. | Period of Glory |
| 69. | Someone to Protect |
| 70. | Forgotten Nation |
| 71. | Older Brother`s Big Rampage |
| 72. | Something that Must be Sealed |
| 73. | The Beating of Darkness |
| 74. | The Governor of Truth |
| 75. | The Sun and the Moon |
| 76. | Inside the Darkness |
| 77. | The Devil`s Descent |
| 78. | Until the Day We Meet Again |
| 79. | Maou, Again |
| 80. | The Requirements of a Maou |
| 81. | Decision of the Maou |
| 82. | Greta and Yuuram |
| 83. | Laila`s Marriage |
| 84. | Infiltration! Big Shimaron |
| 85. | The Night of the Banquet |
| 86. | The Captured Maou |
| 87. | Black Janeus |
| 89. | Conrad and Guenter |
| 90. | Anissina the Bride!? |
| 91. | The Hero and the Three Swords |
| 92. | Shou Shimaron`s King, Saralegui |
| 93. | Moon Reflected in Water |
| 94. | The Wind`s Lullaby |
| 95. | The Wincott Inheritance |
| 96. | Invitation to Small Shimaron |
| 97. | The Two Kings |
| 98. | The King`s Guardian |
| 99. | For the Sake of a Friend |
| 100. | A Bitter Farewell |
| 101. | People of the Round Table |
| 102. | El`s Kidnapping |
| 103. | The Chosen One |
| 104. | Pursuit Across The Plains |
| 105. | The White Crow |
| 106. | Holy Sword |
| 107. | Invocation |
| 108. | The Edge of Imagination |
| 109. | Starting a War |
| 110. | Quitting as Maou |
| 111. | A Blue Wind Blowing Through |
| 112. | An Unexpected Union |
| 113. | The Holy Kingdom |
| 114. | The Unfulfilled Promise |
| 115. | The Power of Truth |
| 116. | Sad Howl |
| 117. | A Place to Return to |
| OP: | #1:"Hateshinaku Tooi Sora ni" (果てしなく遠い空に) by The Stand Up (eps 1-78) #2:"Sekai yo Warae" (世界よ笑え) by Jungo Yoshida with M-Tone |
| ED: | #1: "Suteki na Shiawase" (ステキな幸せ) by The Stand Up (eps 1-39) #2: "Arigatō—" (ありがとう〜) by BON'z (eps 40-78) #3:"Going" by Jungo Yoshida |
Sakurai Takahiro   : | Shibuya Yuuri |
| Ohtsuka Akio : | Lord Gwendal von Voltaire |
| Inoue Kazuhiko : | Lord Gunter von Christ |
| Saiga Mitsuki : | Lord Wolfram von Bielefeld |
| Morikawa Toshiyuki : | Sir Conrad Weller |
| Hirata Hiroaki : | Gegenhuber Griesela |
| Miyata Kouki : | Murata Ken |
| Terasoma Masaki : | Lord Adalbert von Grantz |
| Katsuki Masako : | Lady Cecilie "Celi" von Spitzweg |
| Takayama Minami : | Lady Anissina von Karbelnikoff |
| Kakazu Yumi : | Shibuya "Jennifer" Miko |
| Konishi Katsuyuki : | Shibuya Shouri |
| Tsujitani Kouji : | Shibuya Shouma |
| Ishizuka Yoshinori : | Lord Stoffel von Spitzweg |
| Mizuno Risa : | Lady Susannah Julia von Wincott |
| Takeda Masanori : | Jozak Guriere |
| Kumai Motoko : | Greta |
| Yukana : | Ulrike |
| Hashi Takaya : | Bob |
| Matsuyama Takashi : | Dacascos |
| Taguchi Hiroko : | Gisela |
| Sasaki Nozomu : | Daikenja |
| Miki Shinichiro : | Shinou |
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